Thus, hydrogeninduced cracking hic is a major problem in the gas and oil. Hydrogen induced cracking hic or stepwise cracking swc is a specific kind of hydrogen provoked damage in carbon and low alloy steels operating in hydrogen sulphide containing environments, especially in steels used for pipelines and pressure vessels in oil and refinery industry. Metallurgical factors in stress corrosion cracking scc. It is characterized by the brittle fracture of a normally ductile alloy under sustained load in the presence of hydrogen. Blisters appear in many materials in the absence of external stress when the hydrogen. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Pdf hydrogen induced cracking safe materials operating. Stressoriented hydrogeninduced cracking of l360qs steel. Elements hic tests evaluate material susceptibility to hydrogen induced cracking in a sour environment in accordance with nace tm0284. Similarities with hydrogen induced cracking hic, also termed hydrogen induced cracking or stepwise cracking were noted, and the solution was considered to be use of hic resistant steels.
In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. In this project hydrogen charged samples of alloy 718 and alloy 725 have been exposed under tensile stress to establish critical stress levels for initiation of hisc. Large manganese sulphides were found in metallographic specimens not initiating any cracks. Hydrogen induced cracks either follow a linear or stepwise path within the material, hence the term stepwise cracking. According to hic and ssc laboratory tests and also with regard to cost of engineering materials, it was evident that the best alternative for the valve body alloy is a217 wc9. Environmentally assisted cracks in linepipe steels are initiated either as a result of stresses in combination with environmental effects, as in stress corrosion cracking scc, or as a result of trapped hydrogen in the steel, as in hydrogeninduced cracking hic. Hydrogen induced cracking steel features, applications and. Hydrogen embrittlement occurs in a number of forms but the common features are an applied tensile stress and hydrogen dissolved in the metal. Mechanisms that have been proposed to explain embrittlement include the formation of brittle hydrides, the creation of voids that can lead to bubbles and pressure buildup within a material and e. That means the hydroxyle ions decharge separately one by one. May 22, 2018 hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan. Generally, the threshold stress decreases as the yield strength and tensile strength of an alloy increase. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen.
The movement of mobile atomic hydrogen through steel, known as hydrogen permeation, is a prerequisite for most types of hydrogen damage, including hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic and disbonding. Environmental cracking is a broad term that includes corrosion fatigue, hightemperature hydrogen attack, hydrogen blistering, hydrogen embrittlement, liquid metal embrittlement, season cracking, caustic. Environmentally assisted cracks in linepipe steels are initiated either as a result of stresses in combination with environmental effects, as in stress corrosion cracking scc, or as a result of trapped hydrogen in the steel, as in hydrogen induced cracking hic. A test project to examine the susceptibility of hydrogen induced stress cracking hisc has been executed. History, costs, causes, prediction and trends less frequent incidence but a. Stressorientated hydrogen induced cracking sohic susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. The stressstrain curves of the specimens loaded in air before and after charging with various current densities i are shown in fig. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Hydrogeninduced cracking an overview sciencedirect topics.
Unstressed test specimens are exposed to a solution at temperature of 25deg cent with continuous h2s gas flow. Pdf hydrogen induced cracking analysis of a pressure vessel. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after. Hisc hydrogen induced stress considerations 1 day course. Hisc hydrogen induced stress cracking all acronyms. Hydrogen induced cracking hic test tanks are used to study corrosive and embrittling effects on metal samples in hydrogen enriched sour service environments. Overview of stressoriented hydrogen induced cracking sohic. The list of acronyms and abbreviations related to hisc hydrogen induced stress cracking. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry. This can occur during elevatedtemperature thermal treatments and in service during electroplating, contact with maintenance chemicals, wet h 2 s, corrosion reactions, cathodic protection, and operating in highpressure hydrogencontaining environments. Hydrogen induced cracking hic assessment in a gas processing plant case study mohammed a abufour, mohammad. The path of crack growth in hydrogen embrittled steels is a function of the stress intensity factor, k mpavm.
The differences between the flow stresses at point a before unloading and the yield strengths at point b after charging are the hydrogeninduced stresses. Hydrogen induced cold cracking in a low alloy steel a special test procedure was devised to permit obser vation of the precise location and the mechanism of cold cracking by w. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Susceptibility to sohic for linepipepressure vessel steels twi. Susceptibility to hydrogen induced stress cracking of. No applied stresses are required for cracks to appear. It can occur at relatively low temperatures, largely as a result of atomic hydrogen from wet h2s corrosion reactions which enter the steel and collect at inclusions or. Corrosionpedia what is hydrogeninduced cracking hic. Hic resistant material reduces the effects of hydrogen induced cracking in a wet h 2 s or sour service environment.
Metallurgical factors in stress corrosion cracking scc and. Simply put, hydrogen induced cracking damage increases as the level of hydrogen sulphide increases. Mar 25, 2009 nonmetallic inclusions can affect resistance of steels to both general and localized corrosion, including pitting corrosion, stress corrosion cracking scc, and hydrogen induced cracking hic. According to iso 15156, hydrogeninduced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. Hydrogen blistering and hydrogen induced cracking hic. Examples of hydrogen embrittlement are cracking of weldments or hardened steels when exposed to conditions which inject hydrogen into the component. Vargas pm, wastberg s and woollin p, stress based design guidelines for hydrogen induced stress cracking hisc avoidance in duplex materials, proc conf omae 200979504. To our surprise, it was not true in the studied case. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. Efc publication 17, 2nd edition, corrosion resistant alloys for oil and gas production. Hydrogen induced crack resistant hic steel plate brown mcfarlane offers the widest range of carbon and stainless steel plate, available exstock. Sintef og ntnu samler 70 internasjonale eksperter og phdkandidater fra 8 land og 3 kontinenter i trondheim for a diskutere miljopavirket brudd, et tema som er relevant innenfor bransjer hvor levetidsforlengelse og integritet av metalliske konstruksjonsmaterialer viktig, v. Hydrogen induced cracking and sulphide stress cracking of.
Stress cracking resistance of various plastics when in contact with. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. It is made up of a series of hic hydrogen induced cracking cracks that are stacked perpendicularly in the direction of through wall cracks and driven by high residual or applied stresses. Toottaall irre eqquuirreemm ennttss ffoorr eeqquuiippmmenntt. Hydrogen induced cold cracking in a low alloy steel.
It is made up of a series of hic hydrogen induced cracking cracks that are. Hydrogeninduced cracking results from atomic hydrogen being absorbed by solid metals. Hydrogen induced cracking of low strength steels in. Stress orientated hydrogen induced cracking sohic is a manifestation of sulfide stress cracking ssc in cmn steels by a mechanism involving the linking of planar cracks normal to the primary. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering due to hic. Hydrogen blistering has been recognized since the 1940s as a problem in vessel handling sour products. Experience has shown that stainless steels can suffer from hydrogen induced stress cracking hisc under cathodic protection in seawater. May 19, 2009 hic is prevalent in wet h 2 s environments, which is often known as sour service and such cracking over a prolonged period of time without inspection, will reach a critical point and the steel component i. The external uniaxial stress affected the number of initial cracks in the hic tests, having. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. This broad term reflects the role of environment plays in the cracking process and the terms now covers all the following.
Sulfide stress corrosion cracking and hydrogen induced. Hydrogen cracking its causes, costs and future occurrence. At intermediate stage adsorbed hydrogen atoms hads are present. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. This is planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the.
It is often assumed that hic is just a subcategory of sulfide stress cracking. Sohic is a type of cracking that can easily lead to failure and needs to be mitigated. Pdf the present work evaluates hydrogen induced cracking in a tripassisted steel with. The results indicate that flow control valve body failed due to combination of hydrogen induced corrosion cracking hicc and sulfide stress corrosion cracking sscc. Hydrogen induced cracking tests were conducted on high strength steels and nickeliron base alloys using the constant displacement boltloaded compact specimen. Hic test, hydrogen induced cracking test, step wise. Hydrogen combines with carbon within the alloy and forms methane. According to iso 15156, hydrogen induced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. Hydrogen induced cracking, sulphide stress cracking and material. Hydrogen induced cracking and sulphide stress cracking of carbonmanganese steels 517 introduction, sulphide inclusions are considered as the most dangerous sites for hic initiation. Hydrogen induced cracking hic on steel for corrosion.
Environmental cracking refers to the brittle fracture of a normally ductile material in which the corrosive effect of the environment is a causative factor. Recent experience has demonstrated the risk of sscc and hic, sometimes known as hydrogen embrittlement he, of low strength steels subject to high residual stress derived from fabrication techniques. Processes or conditions involving wet hydrogen sulfide, i. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Sulfide stress cracking ssc vs hydrogen induced cracking. This paper presents results from a test program examining the hisc susceptibility of 25% cr super duplex stainless steel uns s32750 at temperatures up to 150 0 c. Hydrogen induced cracking of subsea duplex stainless steel twi. Hydrogeninduced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. The presence of hydrogen at high temperature and pressure can cause embrittlement of carbon steel and alloy steels.
Hydrogen embrittlement also known as hydrogen assisted cracking and hydrogeninduced cracking, describes the embrittling of metal after being exposed to hydrogen. Hydrogen induced cracking steel features, applications. Atomic hydrogen is able to permeate into steel and reacts with iron carbides to form methane. Hydrogen embrittlement and stress corrosion cracking. This causes tensile stresses at the centerline and in addition to the shrinkage of the phase. However, under certain stress and material conditions, the cracks can be arranged in a ladderlike array known as stress orientated hydrogen induced cracking sohic. In this study, the hydrogen induced cracking was done by cathodic. It was not until much later, however, that hic started to be investigated and gained recognition as a potential problem in pipelines as a result of pipeline failures. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Hisc hydrogen induced stress cracking design and material considerations 1 day course if you would like further information on this course, please contact yeechin tang. Hic test, hydrogen induced cracking test, step wise cracking. The driving force is the hydrogen pressure, helped by hydrogen embrittlement.
Hydrogen delayed cracking of highstrength weldable steels 7 these reactions take place in two steps. Cracks can develop by both transgranular and intergranular paths. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Another type of hydrogen corrosion, stressorientated hydrogen induced cracking sochic, is normally found in the base metal adjacent to the weld, where the stress point is highest due to the internal pressure of the. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Hydrogen emanating from the external or exit face of a pipe or vessel is known as efflux. Initiation of stress corrosion cracking and hydrogen. This indicates that hydrogen induced crack formation is dominantly stress induced for this steel. Institute of materials science and testing of plastics, university of leoben. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants.
This is planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form hydrogen at trap sites. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Pdf characterization of hydrogen induced cracking in trip. Hydrogen induced cracking hic from advanced ndt solutions. Nace international has adopted the term hydrogeninduced cracking hic. Stressoriented hydrogeninduced cracking an overview.
Study of correlation between hydrogeninduced stress and. Initiation of stress corrosion cracking and hydrogeninduced. Hydrogen cracking in general fabrication and particularly pipeline welding is examined. Part of the hydrogen produced by the cathodic corrosion reaction may permeate the steel by diffusion, and the balance is dissolved in the process electrolyte or released as. Hydrogen induced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. Hydrogen induced cracking tests of high strength steels and. Stressoriented hydrogen induced cracking sohic is a common, insidious form of wet h2s cracking. Cracks are another type of damage hydrogen induced cracking hic. The boltloaded specimen was subjected to both acid and electrochemical cell environments in order to produce hydrogen. Unstressed test specimens are exposed to a solution at temperature of. Specificationsgrades asmeastm saa 516 grades 606570.
Hydrogen induced cracking is associated with absorption of hydrogen and a delayed time to failure incubation time during which hydrogen diffuses into regions of high triaxial stress. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Because stress corrosion cracks frequently initiate at pits, and pits nucleate at sulfides, the presence of sulfides is likely to affect the scc process. Hydrogen induced cracking safe materials operating limits.
1219 1484 200 102 293 1425 1487 331 362 812 1088 889 1352 1295 1226 533 1213 777 1163 333 1057 533 1247 10 1148 985 1063 697 1034 1351 341 679 586 366 33 542 1372 724 912 1395 450 1292 213 408 1306 1205